Is it possible to use the module if my store is in catalog mode?

Creating a quote in the back office and receiving a customer-side request are separate paths.

You can prepare quotes in the back office. In catalog mode, do not rely on the standard add-to-cart and cart-to-quote path: cart and ordering behavior depends on the functions your shop keeps available in that mode.

The simple form remains a separate contact option when enabled and correctly configured. It sends an email request without automatically creating a structured back-office quote: see requests without an account.

Before deploying this setup, test your theme, module links and any existing-cart scenario. Having a quote does not guarantee conversion to an order when checkout is unavailable.

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